Until about 50 years ago, all known superconductors were metals. This made sense, because metals have the largest number of loosely bound "carrier" electrons that are free to pair up and flow as electrical current with no resistance and 100 percent efficiency – the hallmark of superconductivity.
Then an odd one came along – strontium titanate, the first oxidematerialand first semiconductor found to be superconducting. Even though it doesn't fit the classic profile of a superconductor – it has very few free-to-roam electrons – it becomes superconducting when conditions are right, although no one could explain why.
Now scientists have probed the superconducting behavior of its electrons in detail for the first time. They discovered it's even weirder than they thought. Yet that's good news, they said, because it gives them a new angle for thinking about what's known as "high temperature" superconductivity, a phenomenon that could be harnessed for a future generation of perfectly efficient power lines, levitating trains and other revolutionary technologies.
The research team, led by scientists at the Department of Energy's SLAC National Accelerator Laboratory and Stanford University, described their study in a paper published Jan. 30 in the Proceedings of the National Academy of Sciences.
"If conventional metal superconductors are at one end of a spectrum, strontium titanate is all the way down at the other end. It has the lowest density of available electrons of any superconductor we know about," said Adrian Swartz, a postdoctoral researcher at the Stanford Institute for Materials and Energy Science (SIMES) who led the experimental part of the research with Hisashi Inoue, a Stanford graduate student at the time.
"It's one of a large number of materials we call 'unconventional' superconductors because they can't be explained by current theories," Swartz said. "By studying its extreme behavior, we hope to gain insight into the ingredients that lead to superconductivity in these unconventional materials, including the ones that operate at higher temperatures."